Cadmium is toxic, but all the approximately 7 grams of cadmium in one CdTe panel is in the form of a chemical compound cadmium telluride, 23 which has 1/100 th the toxicity of free cadmium. The formation of self-assembling CdSe islands on ZnSe substrates has been reported by Leonardi et al. Cadmium (Cd) is a soft, malleable, bluish white metal found in zinc ores, and to a much lesser extent, in the cadmium mineral greenockite. Another study shows that CdTe PV recycling will add a significant secondary resource of Te which, in conjunction with improved material utilization, will enable a cumulative capacity of about 2 TW by 2050 and 10 TW by the end of the century. More information on processable studies and data-waiving is available in the section help of the ‘Scientific properties’ header. Physical description: Cadmium telluride is a black, dense, cubic crystalline compound that does not occur naturally. R. Corkish, in Reference Module in Earth Systems and Environmental Sciences, 2013. Cadmium-telluride (called cad-tel for short) is a more cost-effective way of making thin-film PVs than the older crystalline silicon design. Alternative polymer encapsulation schemes are also explored for CIGS devices. In ion-assisted doping, ionized and accelerated dopant beams are directed onto a film as it is being grown from the vapor. CdTe modules undercut silicon wafer modules in cost per unit of generating capacity. 4 FIRST AID MEASURES. Ramakrishna, E.W. Toxicology assessment The compound CdTe has different qualities than the two elements, cadmium and tellurium, taken separately. Interestingly, the blinking statistics differed between small clusters of QDs compared to single QDs or large clusters, which allowed this function to serve as a reporter of nanometer-scale changes in QD-labeled TCR organization after T-cell activation by antigen. Cadmium is toxic, but all the approximately 7 grams of cadmium in one CdTe panel is in the form of a chemical compound cadmium telluride, 23 which has 1/100 th the toxicity of free cadmium. The key to that success is the use of 125I-labeled radiopharmaceuticals—125I has emissions that are ideally suited for CdTe's best energy range (27–37 keV). Narita et al (p. 91) also conclude that “Imarad material is probably n-type CZT, since it forms an ohmic contact with a low work function metal such as indium, while it forms a blocking contact with a high work function metal such as gold.” Narita et al experimented with Au contacts on the n-type Imarad crystal (as blocking diode contacts), and these produced excellent spectra, excellent photopeak efficiency, and improved resistivity compared to the standard Imarad indium contacts. This popularity has been driven, in part, by innovations in QD surface modifications, which has facilitated the process of linking them to biological targets; a recent review of this topic has appeared (Bruchez, 2011). (2013). Back contacts to CdTe often involve Cu incorporation (e.g., Cu-doped graphite paste or Cu-doped ZnTe). Cadmium telluride. They state that undoped CdTe is p-type semiconductor, but addition of In creates n-type material. [23], Semiconductor chemical compound used in solar cells, crystal form: [TeH+2]12[CdH2-2][TeH+2]3[CdH2-2][TeH+2]([CdH-2]14)[CdH-2]1[Te+2]5([CdH-2]38)[Cd-2]26[TeH+2]2[CdH-2]([Te+2]4)[TeH+2]1[CdH2-2][TeH+2]3[CdH-2]2[Te+2][CdH-2]([TeH+2]6[CdH-2]([TeH+2])[TeH+2]68)[TeH+2]([CdH2-2]6)[CdH-2]35, Except where otherwise noted, data are given for materials in their, Solubility is below 0.1mg/l which equals a classification as insoluble- reference, "ECHA Substance Registration", "Nomination of Cadmium Telluride to the National Toxicology Program", National Institute for Occupational Safety and Health, "Characterization of M-π-n CdTe pixel detectors coupled to HEXITEC readout chip", "Properties of II-VI Compound Semiconductors", "Evaluating the read-across approach on CdTe toxicity for CdTe photovoltaics", "Scientific Comment of Fraunhofer to Life Cycle Assessement [, "Life Cycle Impact Analysis of Cadmium in CdTe PV Production", "Scientific Review on the Environmental and Health Safety (EHS) aspects of CdTe photovoltaic (PV) systems over their entire life cycle", "Cadmium telluride - Brief Profile - ECHA", "Future recycling flows of tellurium from cadmium telluride photovoltaic waste", "Sustainability metrics for extending thin-film photovoltaics to terawatt levels", CdTe page on the web-site of the Institute of Solid State Physics of the Russian Academy of Sciences (html). It’s harmful if swallowed, and is very toxic to aquatic life. Both methods use sealed quartz containers operated at a pressure near 1 atmosphere. The core emission is typically weak and always unstable and so a “shell” is added to insulate the core. While reasonable stability under operation has been demonstrated for CdTe and CIGS solar cells, the performance of both can degrade in the presence of moisture. Cadmium telluride quantum dots (CdTe QDs) were prepared by chemical reaction and used to fabricate electroluminescence quantum dot hybrid junction device. CdTe comprised 5.5% of global cell production in 2011, down from a … Cadmium can be rinsed into the … QDs are semiconductor nanocrystals, typically a few hundred to a few thousand atoms of cadmium sulfide, cadmium selenide, or cadmium telluride, which have a characteristic emission, due to exciton confinement, based on the size of the particle (first reported by Rossetti, Nakahara, & Brus, 1983). Time-dependent toxicity of cadmium telluride quantum dots on liver and kidneys in mice: histopathological changes with elevated free cadmium ions and hydroxyl radicals Mengmeng Wang,1,2,* Jilong Wang,1,2,* Hubo Sun,1,2 Sihai Han,3 Shuai Feng,1 Lu Shi,1 Peijun Meng,1,2 Jiayi Li,1,2 Peili Huang,1,2 Zhiwei Sun1,2 1Department of Toxicology and Sanitary Chemistry, School of Public Health, … [citation needed] During their operation, these modules do not produce any pollutants,[citation needed] and, furthermore, by displacing fossil fuels, they offer great environmental benefits. CdTe thin-film PV panels consist of layers of CdTe and CdS. Scheiber and Giakos (2001) comment that material type (e.g., p-type, n-type, zinc presence, zinc content, material purity, etc. The highest efficiency CdTe cells operate in a superstrate configuration with light entering through the glass on which the cell is grown. In spite of the high density of grain boundaries in the films, laboratory solar cells with record efficiencies of ∼16.5% (CdTe) and ∼19.5% (CIGS) have been demonstrated. This resulted in complete charge collection and narrow, symmetric photopeaks. However, cadmium telluride has toxicity concerns. Their bright fluorescence signals are stable for hours at a time, allowing for continuous imaging of potentially malignant tissue [103]. Cadmium telluride Implementation: EU Related composition Related composition: Composition 1 Classification open all close all. Courtesy of E. Fortunato et al. Ingestion may cause nausea, salivation, vomiting and diarrhea. Nearly all preparation schemes follow the CdTe growth with an anneal near 400 °C in an atmosphere of CdCl2 and oxygen that promotes grain regrowth, improves the CdTe carrier lifetime, diffuses the junction region, increases p-type conductivity in CdTe, and forms oxides. As long as the radiation was absorbed near the surface, the holes had only a short distance to travel. EC number: 215-149-9 | CAS number: 1306-25-8 . Surface passivation is the process by which the semiconductor surface is rendered inert and does not change semiconductor properties as a result of interaction with air or other materials in contact with the surface or edge of the crystal. (1998). Introduction At present, every year, small‐ and large‐area photovoltaic systems are installed on the basis of cadmium telluride (CdTe)‐containing modules with a power around 3 GWp, Thus, several toxicological studies will be required, focusing on both local and systemic effects, before quantum dots can potentially be used for the diagnosis of cutaneous neoplasms [105]. a. CAS name: Cadmium Telluride (CdTe) b. Once absorbed, Cd is efficiently retained in the human body, in which it accumulates throughout life. Toxicology assessment The compound CdTe has different qualities than the two elements, cadmium and tellurium, taken separately. s, single-carrier-sensing detector geometries are used to produce high resolution spectroscopy; these include coplanar grids, Frisch-collar detectors and small pixel detectors. Electroless Pt is found to have better properties than other materials for HPB CZT. CdTe nanoparticles are regarded as highly toxic (Cho et al., 2007; Zhang et al., 2007), and the mechanisms of toxicity seem to be linked to the physical properties of the particles and both the Cd and Te components (Cho et al., 2007; Su et al., 2010; Yan et al., 2011). The basic structure (Figure 11) has a glass superstrate and a layer of transparent conducting oxide (TCO) as front contact, near-transparent n-type cadmium sulfide (CdS) window layer, p-type CdTe, and metallic rear contact. Hg 1−x Cd x Te or mercury cadmium telluride (also cadmium mercury telluride, MCT, MerCad Telluride, MerCadTel, MerCaT or CMT) is a chemical compound of cadmium telluride (CdTe) and mercury telluride (HgTe) with a tunable bandgap spanning the shortwave infrared to the very long wave infrared regions. The traveling heater method (THM) and the vertical Bridgman method are long-standing growth protocols for the production of CdTe crystals. The new data deal with systemic and reproductive toxicity, acute pulmonary toxicity, and comparative pulmonary absorption, distribution and toxicity … [citation needed] CdTe PV modules that use cadmium as a raw material appear to be more environmentally friendly than all other current uses of Cd. The Imarad technique begins with lower-purity elemental constituents than most growth methods (i.e., fewer “nines”, 99.99 … %) of purity are specified for their cadmium, zinc, and tellurium. For example, QDs were used by Boyle et al. 2016 May 25;11:2319-28. doi: 10.2147/IJN.S103489. The record-efficiency laboratory devices are prepared by high-temperature absorber growth (near 600 °C). without appropriate gloves and other safety precautions). The toxicity is not solely due to the cadmium content. The static renewal test method of acute lethal concentrations determination was used, … Structure of typical CdTe cell. Keywords: cadmium telluride; toxicity; solar cells; solubility elution; pH dependence 1. On the other hand, the higher resistivity of eV Products’ HPB material already has been used successfully in a variety of medical and industrial applications, achieving better energy resolution than the compensated crystals of Imarad. Based on notification of these results to the European Chemicals Agency(ECHA), CdTe is no longer classified as harmful if ingested nor harmful in contact with skin, and the toxicity classification to aquatic life has been reduced… CdTe thin-film laboratory cell efficiency of 18.3% has been achieved, and the record module efficiency currently stands at 15.3%. Indeed, there is a growing body of evidence showing the toxicity of nanomaterials in cell cultures and animal models (as reviewed by Boczkowski and Hoet, 2010). Franc et al., also describe a Bridgman method of growing CdTe:Cl from Te-rich solution. EC#: 215-149-9. AVA Solar’s vice president of marketing, Russell Kanjorski, said cad-tel is a compound that renders the cadmium inert, reducing the risk of contamination versus cadmium alone. Potential restrictions on market growth are the toxicity of cadmium and limited global supply of tellurium. Limitations remain for the use of quantum dots in the diagnosis of cutaneous neoplasms, as heavy metal exposure is cytotoxic. However, Dharmadasa et al., (1994) report aging effects on Sb contacts in n-type CdTe with observed intermixing of the Sb into the bulk material, thereby increasing the effective p-type doping in the n-type material. Following injection into tumors, quantum dots have also been utilized to identify sentinel lymph nodes and enhance precision in mapping lymph nodes [104]. The highest-efficiency CIGS cells are grown by physical vapor deposition and the grain microstructure is defined by a complex evolution from Cu-rich to In- and Ga-rich phases during growth. Formula: CdTe; MW=240 iii. Acute toxicity - dermal Reason for no classification: data conclusive but not sufficient for classification Acute toxicity - inhalation In terms of Cd, it should be noted that it is a by-product of zinc mining. CdTe solar cells are the second most common photovoltaic (PV) technology in the world marketplace after crystalline silicon, currently representing 5% of the world market. In particular, we focus on compound semiconductor detectors. Even with this limitation, CdTe is the detector of choice for one of the most widely used intraoperative probe systems. 1995). Toxicity studies show that CdTe is less toxic than elemental cadmium. B. Mordorski, ... A. Friedman, in Nanoscience in Dermatology, 2016. They are useful as fluorescent markers following excitation by an external light source, and can be used to specifically target tumor biomarkers [17]. Franc et al., (1999) prepared CZT crystals in a vertical arrangement by gradual cooling of the melt—a method called the vertical gradient freeze method. It is converted in the body to dimethyl telluride which imparts a garlic-like odor to the breath and sweat. Among the group II–VI semiconductors, pure and alloyed cadmium telluride (CdTe) films have been the most vigorously investigated. Solar panels have been heralded as the alternative to fossil fuels for decades. and Ho, J. The toxicity issue is controversial and affects public acceptance of the technology. UNSW catalog of solar cell drawings. Cd is primarily toxic to the kidney, especially to the pro … Cadmium telluride (CdTe) (Bonnet (2012))is a direct-bandgap semiconductor with that bandgap well matched to the solar spectrum. The micro- and nanostructures of polycrystalline CdTe have also been investigated (Moutinho et al. The arrangement of p-type and n-type regions being in different materials, known as a heterojunction structure, is fundamentally different from that of the crystalline silicon wafer cell, described above. Copper indium gallium selenide (CIGS) CIGS is another mainstream thin-film technology. Time-dependent toxicity of cadmium telluride quantum dots on liver and kidneys in mice: histopathological changes with elevated free cadmium ions and hydroxyl radicals Mengmeng Wang,1,2,* Jilong Wang,1,2,* Hubo Sun,1,2 Sihai Han,3 Shuai Feng,1 Lu Shi,1 Peijun Meng,1,2 Jiayi Li,1,2 Peili Huang,1,2 Zhiwei Sun1,2 1Department of Toxicology and Sanitary Chemistry, School of Public Health, … Even in the case of a fire, research shows that less than 0.1% of the cadmium is released when a CdTe panel is exposed to fire. Wet chemical processing involves polishing with mildly abrasive chemicals. By limiting the system to 125I, the detector could be relatively thin and low cost and the shielding/colli-mation requires only about 0.2 mm of lead for a factor of 1000 absorption of 125I photons. According to the classification provided by companies to the European Chemicals Agency (ECHA) in REACH registrations, it is still harmful to aquatic life with long lasting effects. CdTe-QD treatment resulted in the enlargement of mitochondria as examined with transmission electron … Common name: Cadmium Telluride (CdTe) c. CASRN: 1306-25-8 d. Chemical Class: Cadmium compounds e. Physical properties i. Typical absorber deposition temperatures are over 500 °C for CIGS and a post-deposition anneal in a Se atmosphere is recommended. Several groups have used QDs and FFS to study receptors. This also means controlled doping, and conductivity is one of the challenges in optimizing cells. Tellurium Compounds: Exposure to tellurium compounds may cause garlic odor of the breath and sweat, dryness of the mouth, metallic taste, somnolence, anorexia, and occasional nausea. Probable reasons include small sticking coefficients for the dopants on a growing surface, evaporation of dopants as molecular species with high dissociation energies, self-compensation in CdTe, and impurities giving rise to amphoteric behavior by being incorporated on more than one site. Additionally, the classification provided by companies to ECHA notifications classifies it as very toxic to aquatic life with long lasting effects, very toxic to aquatic life, harmful if inhaled or swallowed and is harmful in contact with skin. Cadmium telluride (CdTe) is a semiconductor compound used for various applications, including photovoltaic (PV) cells, infrared and radiation detection, and electro-optical modulators. Cadmium Telluride (CdTe) is also available as quantum dots. It can be made into nanocrystals. Keywords acute toxicity, cadmium telluride, inhalation exposure, oral exposure. 7). We studied the effect of cell inhibition with ZnS core quantum dots and CdTe quantum dots modified with Thioglycolic acid or Cysteine functional group (TGA-CdTe, TGA-CdTe/ZnS, Cys-CdTe, Cys-CdTe/ZnS) on Caco-2 cell proliferation. Quantum dots are derived from semiconductor materials, including cadmium selenide, Photovoltaics: Advanced Inorganic Materials, Polycrystalline thin-film solar cells utilizing the II–VI semiconductor, Fluorescence Fluctuation Spectroscopy (FFS), Part B, David M. Jameson, ... Joseph P. Albanesi, in, QDs are semiconductor nanocrystals, typically a few hundred to a few thousand atoms of cadmium sulfide, cadmium selenide, or, Handbook on the Toxicology of Metals (Third Edition), Risk Assessment for Human Metal Exposures. Although there is not a definitive explanation for the beneficial effects of Na, Na is believed to reduce the resistivity of the film. In this study, we evaluated the toxicity of CdTe QDs of different sizes and investigated their mechanism of toxicity in the yeast Saccharomyces cerevisiae . Okamoto et al., (2000) note Cu diffusion and the degradation of photovoltaic performance over time. Advancements in solar technology and the rapidly-expanding landscape of photovoltaic arrays are raising concerns about environmental toxicity — namely the use of Cadmium telluride (CdTe) in most photovoltaic (PV) solar cells.. Gold and platinum are the most commonly used contact materials with CZT (Schlesinger et al., 2001); they are applied through thermal evaporation, sputtering, or elec-troless deposition. Cadmium telluride (CdTe) compound semiconductors for x-ray detectors have experienced a rather rapid development in the last few years, due to their appealing performance. Finally, we note that issues of scarce elements (e.g., In) and toxicity (e.g., Cd) are frequently discussed in the context of both technologies. Cadmium-Telluride (CdTe) Modules. Cadmium telluride | CdTe | CID 91501 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, safety/hazards/toxicity information, supplier lists, and more. 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Cdte thin-film solar cells can be manufactured quickly and inexpensively, providing a lower-cost to. All close all, extending into the bulk of CdTe and CIGS activities, safety/hazards/toxicity information, supplier,. 6N ) CZT polycrystals non-soluble in water the Ames mutagenicity test in doping. Negative in the year 2000 time frame of inflammatory cytokines and prevent cytotoxicity the performance CdTe! Is especially problematic for CdTe cells where s diffusion into the … the toxicity of cadmium chloride content... Vapor pressure of zero at ambient temperatures CdS and the vertical Bridgman method standard..., … cadmium-telluride ( CdTe ) c. CASRN: 1306-25-8, indium phosphide, and.! Emphasis on the drift of charge and signal induction in the solar spectrum 2011... In both Environmental and occupational exposure terms rapidly, but few studies on aging have been most...